A solution of 5.0 g benzoic acid (C6H5COOH) in 100.0 g of carbon tetrachloride has a boiling point of 77.5° C. The boling point of pure CCl4 is 76.5° C. Calculate the molar mass of benzoic acid in the solution based on the boiling point elevation. (Kb for CCl4 is 5.03° C/m.)

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Answer:

The molar mass of benzoic acid is 251.3 g/mol

Explanation:

∆T = m × Kb

m (molality) = ∆T/Kb = (77.5 - 76.5)/5.03 = 1/5.03 = 0.199 mol/kg

Molar mass of benzoic acid = mass of benzoic acid ÷ (molality × mass of CCl4 in kilograms) = 5 ÷ (0.199 × 100/1000) = 5 ÷ 0.0199 = 251.3 g/mol

The molar mass of benzoic acid in the solution based on the boiling point elevation is 251.3 g/mol.

Elevation in boiling point

The elevation in boiling point (ΔTb) is proportional to the concentration of the solute in the solution.

[tex]\triangle T = m * K_b\\\\m= \frac{\triangle T}{k_b}\\\\m=\frac{(77.5 - 76.5}{5.03} )\\\\m=\frac{1}{5.03}\\\\m= 0.199 mol/kg[/tex]

Given:

Mass of benzoic acid= 5.0g

To find:

Molar mass=?

[tex]\text{ Molar mass of benzoic acid} =\frac{\text{mass of benzoic acid}}{(\text{molality *mass of} CCl_4 \text{ in kilograms)} } \\\\\text{ Molar mass of benzoic acid}=\frac{5}{(0.199 × 100/1000)}\\\\\text{ Molar mass of benzoic acid}=\frac{5}{0.0199}\\\\\text{ Molar mass of benzoic acid} =251.3 g/mol[/tex]

Thus, the molar mass of benzoic acid is 251.3 g/mol.

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