How much ice (in grams) would have to melt to lower the temperature of 352 mL of water from 26 ∘C to 4 ∘C? (You must consider the enthalpy in cooling the water, as well as the enthalpy in melting the ice and the enthalpy to heat the melted ice from 0∘C up to the system's final temperature of 4 ∘C. Also assume that the density of water is 1.0 g/mL.)

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Answer:

mass of ice = 92.2 g

Explanation:

[tex]density=\frac{mass}{volume}[/tex]

Volume given = 352 mL

Density of water = 1.0 g/mL

Mass = density × volume

          = 1.0 g/mL × 352 mL

          = 352 g

[tex]q=m\times c\times \Delta t[/tex]

Where,

q = heat given or taken

c = specific heat capacity

Δt = change in temperature

Specific heat capacity = 4.18 J/g°C

First calculate the heat given by water by lowering temperature:

[tex]q=m\times c\times \Delta t\\=352\times 4.18 \times (4-26)\\=-32369.9\ J[/tex]

Heat given by water will be utilized in melting ice.

[tex]q_{ice}=-q_{water}[/tex]

[tex]q_{ice}=n\Delta H_{fus}+m\times c\times \Delta t[/tex]

ΔH(fus)=6020 J/mol

[tex]q_{ice}=n\Delta H_{fus}+m\times c\times \Delta t\\=\frac{m_{ice}}{18} mol \times 6020\ J/mol+m_{ice} \times 4.18 \times (4-0)\\m_{ice}(\frac{1}{18} mol \times 6020\ J/mol+ 4.18 \times (4-0))\\=q_{ice}=-q_{water}\\m_{ice}(334.26+16.72)=-(-32369.9)\\m_{ice}350.98=32369.9\\m_{ice}=92.2\ g)[/tex]

Mass of ice = 92.2 g

Given:

Volume given = 352 mL

Density of water = 1.0 g/mL

Density:

It is defined as the ratio of mass over volume.

[tex]\text{Density}=\frac{\text{Mass}}{\text{Volume}}\\\\\text{Mass}=\text{Density}*\text{Volume}\\\\\text{Mass}=1.0g/mL*352mL\\\\\text{Mass}=352g[/tex]

From, specific heat formula:

The specific heat capacity of a substance is the heat capacity of a sample of the substance divided by the mass of the sample.

Where,

q=m*C*ΔT

q = heat given or taken

C = specific heat capacity

ΔT = change in temperature

Specific heat capacity  = 4.18 J/g°C

On substituting the values:

First calculate the heat given by water by lowering temperature:

[tex]q=m*C*\triangle T\\\\q=352*4.18*(4-26)\\\\q=-32369.9J[/tex]

Heat given by water will be utilized in melting ice:

[tex]q_{ice}=-q_{water}\\\\q_{ice}=n\triangle H_{fus}+m*C*\triangle T\\\\H_{fus}=6020J/mol\\\\q_{ice}=n\triangle H_{fus}+m*C*\triangle T\\\\q_{ice}=\frac{m_{ice}}{18}mol*6020J/mol+m_{ice}*4.18*(4-0)\\\\q_{ice}=m_{ice}(\frac{1}{18} *6020J/mol+m_{ice}*4.18*(4-0))\\\\q_{ice}=-q_{water}\\\\m_{ice}*(334.26+16.72)=-(-32369.9)\\\\m_{ice}*(350.98)=32369.9\\\\m_{ice}=92.2g[/tex]

Thus, mass of ice that is required to lower the temperature will be 92.2 grams.

Find more information about "Density" here:

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