Complete and balance the following redox equation. What is the coefficient of H2S when the equation is balanced with the set of smallest whole numbers?
H2S + MnO4-® Mn2+ + SO42– (acidic solution)

Respuesta :

Answer:

The balanced reaction is:

[tex]8MnO_{4}^{-}+14H^{+}+5H_{2}S--->8Mn^{+2}+12H_{2}O+5SO_{4}^{-2}[/tex]

The coefficient is "5".

Explanation:

The reaction is in acidic medium.

The oxidized species is S and the reduced one is Mn

The reduction half equation is:

[tex]MnO_{4}^{-}--->Mn^{+2}[/tex]

The Mn atom is already balanced, let us balance oxygen atom by adding four water molecules on right side  and then hydrogen atom by adding hydrogen ions on other side.

[tex]MnO_{4}^{-}+8H^{+}--->Mn^{+2}+4H_{2}O[/tex]

The charge will be balanced by adding electrons to the side with more positive charge.

[tex]5e+MnO_{4}^{-}+8H^{+}--->Mn^{+2}+4H_{2}O[/tex]

The oxidation half reaction is:

[tex]H_{2}S--->SO_{4}^{-2}[/tex]

Again we will balance oxygen with water and hydrogen with hydrogen ions and charge by electrons

[tex]H_{2}S+4H_{2}O--->SO_{4}^{-2}+10H^{+}+8e[/tex]

Now we will multiply the oxidation half reaction with "5" and reduction half reaction with "8" (to balance the electrons) and will add them.

The resulting equation will be:

[tex]8MnO_{4}^{-}+14H^{+}+5H_{2}S--->8Mn^{+2}+12H_{2}O+5SO_{4}^{-2}[/tex]

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