Answer: Option (d) is the correct answer.
Explanation:
A change that does not cause any difference in chemical composition of a substance are known as physical change.
For example, shape, size, mass, volume, density, etc of a substance are all physical changes.
And, a change that causes changes in chemical composition of a substance is known as chemical change.
For example, precipitation, reactivity, toxicity etc are chemical change.
Therefore, change in temperature, chemical precipitation of a solid , production of a gas are all indications of a chemical change.
Thus, we can conclude that change in volume would not necessarily indicate a chemical reaction.