This is because removing three electrons means third ionization energy would leave scandium with a full valence shell that is 3s²3p⁶ and removing a fourth electron would begin to remove electrons from a full valence shell which is very energetically not favorable.
Removing a third and fourth electron from
titanium is bringing Ti closer and closer to having an empty 4th energy
level and a completely full 3rd energy level. Removing the 4th
electron would be very energetically favorable because it would result in a full
valence shell.