Respuesta :
Answer:
CuX = Cu2+ + X2-
Ksp = [Cu2+] * [X2-]
for each mole of CuX that dissolves we get x mol of each of the anions and cations
Ksp = x^2 = 1.27 x 10 ^-36
x= 1.13 x 10 ^-18 moles of CuX per liter of pure water
if the solution has [Cu2+]= 0.27 M
Ksp becomes x ( x + 0.27)
as we can see above x is extremely small so can be ignored inside the brackets
0.27 x = 1.27 x 10^-36
x = 1.27 x 10^-36 / 0.27 = 4.70 x 10 ^-36 moles per liter
In 0.19M X2- we have
Ksp = 0.19x = 1.27 x 10^-36
x = 1.27 x 10^-36 / 0.19 = 6.68 x 10 ^-36 moles per liter
The molar solubility of CuX : 1.127.10⁻¹⁸ mol/L
Further explanation
Solubility(s) is the maximum amount of a substance that can dissolve in some solvents.
Ksp is an ion product in equilibrium
Solubility (s) and solubility constants (Ksp) of the AxBa solution can be stated as follows.
AₓBₐ (s) ← ⎯⎯⎯⎯ → aAᵃ⁺ (aq) + b Bᵇ⁻ (aq)
s as bs
Ksp = [Aᵃ⁺]ᵃ [Bᵇ⁻]ᵇ
Ksp = (as)ᵃ (bs)ᵇ
Solubility units in the form of mol / liter or gram / liter
Ksp is the product of ions in an equilibrium saturated state
The molar solubility of CuX in pure water
Reaction
CuX ⇔ Cu²⁺ + X²⁻
s s s
Ksp = s²
1.27×10⁻³⁶ = s²
[tex]\rm s=\sqrt{1.27.10^{-36}}\\\\s=1.127.10^{-18}\:\dfrac{mol}{liter}[/tex]
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