Whitney has 0.026 moles of O2 in her lungs.
The ideal gas law is
PV = nRT
where
P = Pressure
V = volume
n = Number of moles
R = Ideal Gas Constant (0.082057338 L*atm/(K*mol) )
T = Absolute temperature
Since a mmHg is 1/760 atm, the pressure is 747/760 atm = 0.982894737 atm
Converting 37C to K, 37 + 273.15 = 310.15 K
Now let's take the ideal gas equation, solve for n, the substitute the known values and solve.
PV = nRT
PV/RT = n
(0.982894737 atm)(3.2 L)/((0.082057338 L*atm/(K*mol))310.15 K) = n
(3.145263158 atm*L)/(25.45008338 L*atm/mol) = n
0.123585574 mol = n
So there's 0.123585574 moles of gas particles in Whitney's lungs. Let's get the moles of oxygen
0.123585574 mol * 0.21 = 0.02595297 mol
Rounding to 2 significant figures gives 0.026 moles.