Respuesta :
If the enthalpy of thermodynamic delta H and the entropy of evaporation delta S is known set the Gibbs free energy of the evaporation delta.
G = delta H minus T delta S = 0. increase.
The boiling point temperature is T = delta H/delta S. Trouton's law, which states that the entropy of vaporization for many substances at one atmosphere of pressure is about 21 cal/deg-mole, can be helpful for values of delta S. Not available for tables.
The Gibbs free energy of a system at any point in time is defined as the enthalpy of the system minus the product of the temperature and the entropy of the system. So, to a first approximation, the vaporization enthalpy of a liquid is proportional to the thermodynamic temperature at which the liquid boils.
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