calculate δg∘rxn and k for each of the following reactions. part a part complete the reaction of cr2 (aq) with cr2o2−7(aq) in acid solution to form cr3 (aq) . calculate δg∘rxn .

Respuesta :

The ΔG° r×n is gven as - 1059.42 KJ

The chemical equation is given as :

[tex]6Cr{2}^{+} + Cr{2}O{7}^{2-} + 14H^{+} -------- > 8Cr^{3+} + 7HO{2}[/tex]

ΔG r×n = - nFEcell

Ecell =  Eoxidation + Ereduction

Eoxidation = -Ereduction =-(-0.50V) =  0.50 V

Ereduction = 1.33 V

Ecell  =  0.50 V + 1.33 V

         =   1.83 V

now, putting the value in formula

ΔGr×n = -nFEcell

where , n= 6 , f = faraday's constant = 96485 C/mol, Ecell = 1.83 V

therefore, ΔG r×n = - 6× 96487 × 1.83

                              = -1059.42 KJ

Now, ΔG°r×n = ΔG + RTlnQ

for standard condition Q = 1

hence ΔG°r×n = - 1059.42 KJ

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