Cscl has a crystal stucture where each cl- ion is surrounded by 8 cs+ ions.
Caesium (Cs+) and chloride (Cl-) ions make up an equal amount of the crystals in caesium chloride. Two ions' radii—169 pm for Cs+ and 181 pm for Cl-—led to a radius ratio of 0.93, which suggests a body-centered cubic structure with a cubic hole.
The minimal ratio is 169/181 = 0.93 for rCs+/rCl-.
What is CsCl structure?
The physical makeup of calcium chloride, abbreviated CsCl. An unending chain of ions makes up the cubic structure of csCl. The cube's eight corners contain Cs (or Cl) ions, while the cube's centre contains Cl (or Cs) ions (thus it is NOT a body-centered lattice since that requires the SAME ion to occupy the edges and center).
Caesium (Cs+) and chloride (Cl-) ions make up an equal amount of the crystals in caesium chloride. Two ions' radii—169 pm for Cs+ and 181 pm for Cl-—led to a radius ratio of 0.93, which suggests a body-centered cubic structure with a cubic hole.
Thus the minimal ratio is 169/181 = 0.93 for rCs+/rCl-.
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