Calculate the ph of a mixture of 0.25 m acetic acid (ch3cooh) and 0.1 m sodium acetate (ch3coo- na ) in a total volume of 1 l. the pka of acetic acid is 4.76.

Respuesta :

The pH of a mixture of 0.25 m acetic acid (CH3COOH) and 0.1 m sodium acetate (CH3COO- Na ) in a total volume of 1 l is 4.37.

The above situation represents a case of buffer solution.

Buffer solutions are those solutions that can resist change in their pH if any acid or base is added to them.

To calculate the pH of a buffer solution, the Henderson-Hasselbalch equation is used

pH = pKa + log [Salt]/[Acid]

Putting

pKa = 4.76

[Salt] = Concentration of sodium acetate = 0.1 M

[Acid] = Concentration of acetic acid = 0.25 M

pH = 4.76 + log [0.1]/[0.25]

pH = 4.76 + log[0.4]

pH = 4.76 - 0.39

pH = 4.37

Hence, the pH of a mixture of 0.25 m acetic acid (ch3cooh) and 0.1 m sodium acetate (ch3coo- na ) in a total volume of 1 l is 4.37.

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