The value of Kb of the unknown amine is 3.22 x 10^-4.
Weak electrolytes:
The compound which do not dissociate completely when added to the aqueous solution are called weak electrolytes. The electrolyte and its ions exists in equilibrium. In case of weak base, the equilibrium constant is expressed as Kb.
Calculations:
Step 1:
The percentage of amine ionized at equilibrium is 2.2%.
NH3 + H2O ------> NH4+ + OH-
The concentration of conjugate acid at equilibrium is calculated as:
2.2 = (x/0.65) x 100
x = 0.0143 M
Step 2:
The equilibrium constant (Kb) is calculated as:
Kb = x^2/0.65 - x
= (0.0143)^2/(0.65 - x)
= 3.22 x 10^-4
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