A silicon atom has four unpaired electrons in its valence shell, two paired electrons in its inner shell, and 14 electrons in all. There are 4 hydrogens it will form covalent bonds with.
The four electrons that make up the "valence" energy level's outermost orbit of the nucleus are given to, taken from, or shared by other atoms. Dependent on their energy level, the electrons orbit the nucleus at various distances. As an illustration, an electron with lower energy would orbit towards the nucleus, whereas an electron with higher energy would orbit farther away. The interaction between the electrons of nearby atoms and those that are the farthest from the nucleus determines how solid structures are created.
The first practical PV devices were made of crystalline silicon, which is still the most used PV material in use today. Grasp how the PV effect functions in crystalline silicon provide us a fundamental understanding of how it functions in all devices, even though various PV materials and designs utilize the effect in slightly different ways.
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