To give 33.6 dm³ hydrogen gas at STP, 18.06 x 10²³ atoms of Na must react completely.
A mole is a unit of measurement used to measure the amount of any fundamental entity (atoms, molecules, ions) present in the substance.
As according to the given equation, 2 moles (ie 12.04 x 10²³ atoms) of Na-atoms produces 1 mole (22.4 ltr) of H₂-gas.
Hence, to produce 33.6 ltr (equivalent to 33.6 dm³) of H₂-gas produced by ;
= 12.04 x 10²³ atoms of Na / 22.4 ltr of H₂-gas x 33.6 ltr
= 18.06 x 10²³ atoms of Na
Hence, To give 33.6 dm³ hydrogen gas at STP, 18.06 x 10²³ atoms of Na must react completely.
Learn more about Mole concept here ;
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