The boiling point of HF is higher than the boiling point of [tex]H_2[/tex], and it is higher than the boiling point of [tex]F_2[/tex].
The boiling point is the temperature at which the pressure exerted by the surroundings upon a liquid is equalled by the pressure exerted by the vapour of the liquid.
[tex]F_2[/tex] has weak dispersion force attractions between its molecules, whereas liquid HF has strong ionic interactions between [tex]H^+[/tex] and [tex]F^-[/tex] ions.
Only London Forces are formed - Therefore more energy is required to break the intermolecular forces in HF than in the other hydrogen halides and so HF has a higher boiling point.
[tex]H_2[/tex] and [tex]F_2[/tex] will only have intra-molecular attractions and there will be no hydrogen bonds present in them. As a result, their boiling point will be lower.
Hence, the boiling point of HF is higher than the boiling point of [tex]H_2[/tex], and it is higher than the boiling point of [tex]F_2[/tex].
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