Benzilic acid will only precipitate in acidic solution to remove excess acid and restore equilibrium.
Chemical equilibrium refers to a state in which the rate at which reactant molecules combine to form products is equal to the rate at which products dissociate to form reactants.
For a reaction in equilibrium, any change to distort the equilibrium will cause equilibrium to shift to counter that change.
The components of Benzilic acid exist in equilibrium and will only precipitate in acidic solution because more acid has been added and equilibrium will shift to removal of excess acids.
Therefore, benzilic acid only precipitate in acidic solution in order to remove excess acid and restore equilibrium.
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