Kingsley then adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution. The neutralization reaction resulted in 0.098 moles of HCOOH and 0.025 moles of HCOO left in solution. Determine the pH of the resulting solution. Which of the following acids would produce the highest pH at the equivalence point in a weak acid-strong base titration?
Ka(HF) =6.8x10-4
Ka(HNO2) =4.5x10-4
Ka(HCIO2) =1.1x10-2
K(CH3COOH) =1.8x10-5
i. HCIO2
ii. CH3COOH
iii. HF
iv. HNO2

The Ph value differ for base and acid. A neutral solution will have Ph value of 7. For acid the Ph value is less than 7 and for base Ph value is greater than 7. The highest Ph value for the given acids is 3.27 for hydroflouric acids.

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nainasaini61097 nainasaini61097 · Answer 2 · 2022-03-25T08:47:11+01:00

The pH of the resulting solution is 3.16. Acetic acid having the formula [tex]CH_3COOH[/tex] would produce the highest pH at the equivalence point in a weak acid-strong base titration.

Kingsley adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution.

The neutralization reaction resulted in 0.098 moles of HCOOH and 0.025 moles of HCOO⁻ left in the solution.

We have to determine the pH of the resulting solution and identify the acid that would produce the highest pH at the equivalence point in a weak acid-strong base titration.

What is pH?

pH, a quantitative measure of the acidity or basicity of aqueous or other liquid solutions.

Kingsley adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution.

Total volume of the solution = 49.28 mL + 250.0 mL = 299.28 mL = 0.29928 L

At neutralization point, HCOOH = 0.098 mol = [tex]\frac{0.098\ mol}{0.29928\ L} = 0.32745\ M[/tex]

So, Concentration of HCOOH at neutralization point = 0.32745 M

And [tex]HCOO^-[/tex] at neutralization point = 0.025 mol = [tex]\frac{0.025\ mol}{0.29928\ L} = 0.08353\ M[/tex]

So, Concentration of HCOO⁻ at neutralization point = 0.08353 M

Now, [tex]K_a[/tex] value of HCOOH = [tex]1.77\times10^{-4}[/tex] (reference value}

We know that [tex]pK_a = -logK_a[/tex]

[tex]pK_a = -log(1.77\times10^{-4}) = 3.75[/tex]

Now, HCOOH is acid and HCOO⁻ is the conjugate base.

According to Henderson Hasselblach equation:

[tex]pH = pK_a + log\frac{[conjugate\ base]}{[acid]}\\ \therefore pH = 3.75 + log\frac{[HCOO^-]}{[HCOOH]}\\pH = 3.75 + log(\frac{0.08353}{0.32745})\\pH = 3.75 +(-0.59)\\pH = 3.16[/tex]

Therefore, the pH of the resulting solution is 3.16.

When weak acid is titrated with a strong base, the pH at the neutralization point is always greater than 7. It is because the conjugate base produced by weak acid in neutralization reaction is comparatively stronger in nature which produces [tex]OH^-[/tex] at neutralization point after reacting with water. so the solution is basic. As a result, pH is more than 7.

Now, the weaker is the acid, the stronger is the conjugate base, and vice-versa. Therefore, the concentration of [tex]OH^-[/tex] ions is more at the neutralization point. So more will be the pH value.

Given acids with the corresponding [tex]K_a[/tex] value are shown below:

[tex]K_a(HF) =6.8\times10^{-4}\\K_a(HNO_2) =4.5\times10^{-4}\\K_a(HClO_2) =1.1\times10^{-2}\\K_a(CH_3COOH) =1.8\times10^{-5}[/tex]

We know that lower the value of [tex]K_a[/tex] of acid, the weaker is the acid and vice-versa. Hence, [tex]CH_3COOH[/tex] has lowest [tex]K_a[/tex] value compared to other acids. Therefore, [tex]CH_3COOH[/tex] would produce the highest pH at the equivalence point in a weak acid-strong base titration.

Hence, The pH of the resulting solution is 3.16. Acetic acid having the formula [tex]CH_3COOH[/tex] would produce the highest pH at the equivalence point in a weak acid-strong base titration.

To learn more about, acid-base titrations, click here:

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