Which of the following solutes will lower the freezing point of water the most?

A) the molecular compound sucrose (C₁₂H₂₂22O₁₁)

B) the iconic compound magnesium sulfate (MgSO₄4)

C)the iconic lithium chloride (LiCI)

D)the iconic compound calcium fluoride(CaF₂2)

Respuesta :

Answer: D) the iconic compound calcium fluoride (CaF₂)

Explanation:

[tex]\Delta T_f=i\times k_f\times m[/tex]

where,

[tex]\DeltaT_f[/tex] = change in freezing point

i= vant hoff factor

[tex]k_f[/tex] = freezing point constant

m = molality

A) the molecular compound sucrose (C₁₂H₂₂O₁₁)

: For non electrolytes like sucrose, vant hoff factor is 1.

B) the iconic compound magnesium sulfate (MgSO₄): For electrolytes, vant hoff factor is equal to the number of ions it produce on dissociation.

[tex]MgSO_4\rightarrow Mg^{2+}+SO_4^{2-}[/tex]    Thus i= 2

C) the iconic lithium chloride (LiCI):

[tex]LiCl\rightarrow Li^++Cl^-[/tex], thus  i=2.

Thus 1% produces most ions and thus lowers the freezing point to maximum.

D) the iconic compound calcium fluoride(CaF₂):

[tex]CaF_2\rightarrow Ca^{2+}+2F^-[/tex], thus  i=3.

Thus the compound with highest value of i, will depress the freezing point to maximum.

Answer:

D) the iconic compound calcium fluoride (CaF₂)

Explanation:

I took the test and got it right