The organic compounds that are capable of being a reactant in all substitution reactions would belong to the alkane group.
Alkanes are saturated compounds that ordinarily will not participate in addition reactions due to their saturated nature.
Thus, alkanes are only able to participate in substitution reactions involving the substitution of one or more of their component atoms for another atom.
This is unlike alkyne and alkenes which are naturally unsaturated. The unsaturation makes them a candidate for additional reactions.
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