Answer:
The common oxide of nitrogen that has a positive ΔS°f is nitric oxide (NO)
Explanation:
Without reference to thermodynamic data, we have;
1) N₂ (g) + O₂ (g) ⇄ 2 NO (g)
1 unit of N₂ + 1 unit of O₂ (total of 2 units) gives 2 units of NO, (Increase of +0 disorder)
∴ΔS°f = +ve
2) 2NO + O₂ → 2NO₂
2 unit of NO + 1 unit of O₂ (total of 3 units) gives 2 units of NO₂, (Decrease of disorder)
∴ΔS°f = -ve
3) N₂ + 1/2 O₂ → N₂O
1 unit of N₂ + 1/2 unit of O₂ (total of 1+1/2 units) gives 2 units of NO₂, (Decrease of disorder)
∴ΔS°f = -ve
4) 4 NO₂ + O₂ → 2N₂O₅
4 unit of NO₂ + 1 unit of O₂ (total of 5 units) gives 2 units of N₂O₅, (Decrease of disorder)
∴ΔS°f = -ve
5) NO + NO₂ ⇄ N₂O₃
1 unit of NO + 1 unit of NO₂ (total of 2 units) gives 1 unit of N₂O₃, (Decrease of disorder)
∴ΔS°f = -ve
Therefore, the common oxide of nitrogen that has a positive ΔS°f without reference to thermodynamic data is nitric oxide NO.
The common oxide of nitrogen that has a positive ΔS°f is Nitric oxide
(NO).
This is defined as the degree of randomness or disorderliness in a system
and it is denoted by S.
The reaction involving the formation of Nitric oxide can be seen below:
N₂ (g) + O₂ (g) ⇄ 2 NO (g)
1 mole of N₂ + 1 mole of O₂ (total = 2 moles) gives 2 moles of NO which
means that there was an Increase of +0 disorder.
This therefore means S is positive.
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