Answer:
The water takes longer, because it is the better insulator here.
Explanation:
Conductors and insulators work similarly in "reverse".
If something is a good heat conductor, then it's good at both absorbing heat energy and giving it away. Insulators are good at resisting temperature changes, but also take longer to cool down once they are heated up.
So because copper is the better conductor here, it will cool faster than the water at the same temperature.