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Answer:
Here's what I get
Explanation:
You have an equilibrium reaction between Fe³⁺/ SCN⁻ and FeSCN²⁺.
[tex]\underbrace{\hbox{Fe$^{3+}$}}_{\text{pale yellow-green}} +\underbrace{\hbox{SCN$^{-}$}}_{\text{colourless}} \, \rightleftharpoons \, \underbrace{\hbox{Fe(SCN)$^{2+}$}}_{\text{deep blood red}} \\[/tex]
When you add AgNO₃, the Ag⁺ reacts with the SCN⁻. It forms a colourless precipitate of Ag(SCN).
Ag⁺(aq) + SCN⁻(aq) ⟶ AcSCN(s)
According to Le Châtelier's Principle, when we apply a stress to a system at equilibrium, the system will respond in a way that tends to relieve the stress.
If you add Ag⁺ to the equilibrium solution, it removes the SCN⁻ [as an Ag(SCN) precipitate].
The system responds by trying to replace the missing SCN⁻:
The Fe(SCN)²⁺ dissociates to form SCN⁻, so the position of equilibrium shifts to the left,
You now have more Fe³⁺ and SCN⁻ and less of the highly coloured Fe(SCN)²⁺ at the new equilibrium.
The deep red colour becomes less intense.
When silver nitrate is added to the Fe/SCN equilibrium, the colourless intense and precipitate forms because it settles at the bottom.
What is chemical equilibrium?
Chemical equilibrium is the condition in the course of a reversible chemical reaction in which no net change in the amounts of reactants and products occurs.
The added silver nitrate, [tex]AgNO_3[/tex] , effectively removes thiocyanate ions, [tex]SCN^{-1}[/tex], from the equilibrium system via a precipitation reaction when the [tex]Ag^{+1}[/tex] combines with [tex]SCN^{-1}[/tex] to produce insoluble silver thiocyanate, AgSCN, which settles to the bottom of the test tube.
Ag⁺(aq) + SCN⁻(aq) ⟶ AcSCN(s)
According to Principle, when we apply stress to a system at equilibrium, the system will respond in a way that tends to relieve the stress.
Adding Ag⁺ to the equilibrium solution, it removes the SCN⁻ [as an Ag(SCN) precipitate].
The system responds by trying to replace the missing SCN⁻:
The Fe(SCN)²⁺ dissociates to form SCN⁻, so the position of equilibrium shifts to the left,
You now have more Fe³⁺ and SCN⁻ and less of the highly coloured Fe(SCN)²⁺ at the new equilibrium.
The deep red colour becomes less intense.
Learn more about chemical equilibrium here:
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