Network solid kind of solid is crystalline boron (B). Hence, option D is correct.
What is Network solid?
A network solid is a solid where all the atoms are covalently bonded in a continuous network.
Boron is a nonmetallic element existing as a dark brown to black amorphous powder or as an extremely hard, usually jet-black to silver-grey, brittle, lustrous, metallike crystalline solid
It is a network solid, a lattice of many covalent bonds (like a diamond, except that it is black rather than transparent).
Hence, option D is correct.
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