The diffusion coefficients for iron in nickel are given at two temperatures:T (K)D (m2/s)12739.4 × 10–1614732.4 × 10–14(a) Determine the values of D0 and the activation energy Qd.(b) What is the magnitude of D at 1100°C (1373 K)?

Respuesta :

Answer:

The diffusion coefficients for iron in nickel are given at two temperatures:

T (K)        1273          1473

D ([tex]m^{2}[/tex]/s) 9.4 × [tex]10^{-16}[/tex]    2.4 × [tex]10^{-14}[/tex]

(a) Determine the values of Do and the activation energy Qd.

(b) What is the magnitude of D at 1100°C (1373 K)?

A

The pre-exponential factor Do = 2.1 x [tex]10^{-16}[/tex]

The activation energy Qd = 252,609 J/mol

B

The diffusion coefficient D= 5.14 x [tex]10^{-15}[/tex]

Explanation:

The full explanation is contained in the attached images;

Ver imagen ezeanakanath
Ver imagen ezeanakanath
Ver imagen ezeanakanath

a)  The value of D0 is 2.18 * 10^-5 m^2 / s while the value of the activation energy is Qd = 252.609 kj/mol

b) The coefficient of diffusion at 100 C is 5.4 * 10^-15 m^2 / s

What is Diffusion?

Diffusion is the movement of a gas from a region of high concentration to that of low cooncetration.

From coefficient of diffusion equation

[tex]D = D_{0} exp(-\frac{Q_{d} }{RT} )[/tex]

D = coefficient of diffusiion

D0 =  pre- exponential factor

Qd =  activation energy of diffusion

R =  gas constant

T = thermodynamic temperature

Given

T1 = 273      

D1 = 9.4 * 10^`-16

T2 = 1473    

D2 = 2.4 * 10^-14  

R = 8.314

D1 = D2 exp ( Qd / R T )

D1 - D2 = exp ( Qd / R T )

Qd = { in ( 2.4 * 10^-16 ) - in ( 9.4 * 10^`-16 ) } * 8.314 ) / ( 1 / 1473 - 1 / 273 )

Qd = 252.609 kj/mol

Pre- exponential factor, D0

D0 = D1 / exp ( - Qd / R T )

D0 = 9.4 * 10^`-16 / exp ( -  252609 / ( 8.314 * 1273)

D0 = 2.18 * 10^-5 m^2 / s

b) magnitude of D at 1100 C

convert to Kelvin: 1100 + 273 = 1373

D3 = D2 / exp ( - Qd / R T )

D3 = 2.4 * 10^-16 exp ( -  252609 / ( 8.314 * 1373 )

D3 = D at 100 = 5.4 * 10^-15 m^2 / s

Read more on Diffusion coefficient here: https://brainly.com/question/13843639