For a reaction in a voltaic cell both ΔH° and ΔS° are positive. Which of the following statements is true?

a. ε°cell will decrease with an increase in temperature.
b. ΔG° > 0 for all temperatures.
c. ε°cell will increase with an increase in temperature.
d. ε°cell will not change when the temperature increases.
e. None of these choices statements is true.

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Answer:

c. ε°cell will increase with an increase in temperature.

Explanation:

Gibbs free energy change: ΔG = ΔH - TΔS. If  If ΔG is positive, then the reaction isn't feasible - it can't happen. For a reaction to be feasible, ΔG has to be negative, as T, the temperature, increases ΔG decreases towards  towards more a negative value and ΔG = - nFE.

a. ε°cell will decrease with an increase in temperature. False

Based on the above explanation, we can see that ε°cell will increase with a a temperature increase.

b. ΔG° > 0 for all temperatures. False

For a reaction to be feasible, ΔG has to be negative.

c. ε°cell will increase with an increase in temperature. TRUE

Based on the above explanation, we can see that ε°cell will increase with a a temperature increase.

d. ε°cell will not change when the temperature increases. False

This is false as ε°cell will increase when the temperature increases

e. None of these choices statements is true. False

Choice statement c is true.

C. ε°cell will increase with an increase in temperature is TRUE

For a response to be feasible, ΔG has to be negative.

Gibbs free force change: ΔG = ΔH - TΔS.

What is a Voltaic cell?

Gibbs free force change: ΔG = ΔH - TΔS. If ΔG is positive, then the response isn't feasible - it can't occur. For a reaction to be feasible, ΔG has to be negative, as T, the temperature, increases ΔG decreases towards more a negative significance and also ΔG = - NFL.

a. ε°cell will decrease with an increase in temperature is False

Established on the above description, we can see that ε°cell will increase with a temperature increase.

b. ΔG° > 0 for all temperatures is False

For a response to be feasible, ΔG has to be negative.

c. ε°cell will increase with an increase in temperature is TRUE.

Based on the above description, we can see that ε°cell will increase with a temperature increase.

d. ε°cell will not change when the temperature increases are False

This is false as ε°cell will rise when the temperature increases

e. None of these choices statements is true. are False

The correct Choice statement c is true.

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