179.1 g of water is in a Styrofoam calorimeter of negligible heat capacity. The initial T of the water is 16.1oC. After 306.9 g of an unknown compound at 94.3oC is added, the equilibrium T is 27.4oC.

What is the specific heat of the unknown compound in J/(goC)?

Respuesta :

Answer:

the specific heat of the unknown compound is [tex]c_u=0.412J/g \cdot C[/tex]

Explanation:

Generally the change in temperature of water is evaluated as

                [tex]\Delta T = T_2 -T_1[/tex]

Substituting 16.1°C for [tex]T_1[/tex] and 27.4°C for [tex]T_2[/tex]

                [tex]\Delta T = 27.4 - 16.1[/tex]

                       [tex]=11.3^oC[/tex]

Generally the change in temperature of  unknown compound is evaluated as

                  [tex]\Delta T_u = T_3 -T_2[/tex]

Substituting 27.4°C for [tex]T_2[/tex] and 94.3°C for [tex]T_3[/tex]

                                    [tex]\Delta T = 94.3 - 27.4[/tex]

                                           [tex]=66.9^oC[/tex]

Since there is an increase in temperature then heat is gained by water and this can be evaluated as

               [tex]H_w = mc_w \Delta T[/tex]

Substituting 179.1 g  for m , 4.18 J/g.C for [tex]c_w[/tex](specific heat of water)

             [tex]H_w = 4.18 * 179.1 * 11.3[/tex]

                   [tex]= 8459.6J[/tex]

Since there is a decrease in temperature then heat is lost by unknown compound and this can be evaluated as

                    [tex]H_u = m_uc_u \Delta T_u[/tex]

By conservation of energy law

       Heat lost  = Heat gained  

Substituting 306.9 g  for [tex]m_u[/tex] , 8459.6J for [tex]H_u[/tex]

           [tex]8459.6 = 306.9 * c_u * 66.9[/tex]

  Therefore     [tex]c_u = \frac{8459.6}{308.9 *66.9}[/tex]

                           [tex]=0.412J/g \cdot C[/tex]