How many milliliters of 0.105 M HCl are needed to titrate each of the following solutions to the equivalence point?

a. 50.0 mL of 9.5010?2 M NaOH

b. 23.0 mL of 0.117 M NH3

c. 130 mL of a solution that contains 1.40 g of NaOH per liter

Respuesta :

Answer:

For a: The volume of HCl needed is 4.52 mL

For b: The volume of HCl needed is 25.63 mL

For c: The volume of HCl needed is 43.33 mL

Explanation:

To calculate the volume of acid, we use the equation given by neutralization reaction:

[tex]n_1M_1V_1=n_2M_2V_2[/tex]

where,

[tex]n_1,M_1\text{ and }V_1[/tex] are the n-factor, molarity and volume of acid

[tex]n_2,M_2\text{ and }V_2[/tex] are the n-factor, molarity and volume of base

  • For a:

We are given:

[tex]n_1=1\\M_1=0.105M\\V_1=?mL\\n_2=1\\M_2=9.50\times 10^{-2}M=0.00950M\\V_2=50.0mL[/tex]

Putting values in above equation, we get:

[tex]1\times 0.105\times V_1=1\times 0.00950\times 50\\\\V_1=\frac{1\times 0.00950\times 50}{1\times 0.105}=4.52mL[/tex]

Hence, the volume of HCl needed is 4.52 mL

  • For b:

We are given:

[tex]n_1=1\\M_1=0.105M\\V_1=?mL\\n_2=1\\M_2=0.117M\\V_2=23.0mL[/tex]

Putting values in above equation, we get:

[tex]1\times 0.105\times V_1=1\times 0.117\times 23\\\\V_1=\frac{1\times 0.117\times 23}{1\times 0.105}=25.63mL[/tex]

Hence, the volume of HCl needed is 25.63 mL

  • For c:

To calculate the molarity of solution, we use the equation:

[tex]\text{Molarity of the solution}=\frac{\text{Mass of solute}}{\text{Molar mass of solute}\times \text{Volume of solution (in L)}}[/tex]

Given mass of NaOH = 1.40 g

Molar mass of NaOH = 40 g/mol

Volume of solution = 1 L

Putting values in above equation, we get:

[tex]\text{Molarity of NaOH solution}=\frac{1.40}{40\times 1}\\\\\text{Molarity of NaOH}=0.035M[/tex]

We are given:

[tex]n_1=1\\M_1=0.105M\\V_1=?mL\\n_2=1\\M_2=0.035M\\V_2=130mL[/tex]

Putting values in above equation, we get:

[tex]1\times 0.105\times V_1=1\times 0.035\times 130\\\\V_1=\frac{1\times 0.035\times 130}{1\times 0.105}=43.33mL[/tex]

Hence, the volume of HCl needed is 43.33 mL

a: The volume of HCl is 4.52 mL

b: The volume of HCl is 25.63 mL

c: The volume of HCl  is 43.33 mL

Calculation for volume of acid:

It is given by the formula for dilution or neutralization reaction:

n₁*M₁*V₁= n₂*M₂*V₂

where,

n₁, M₁ ,V₁ are the n-factor, molarity and volume of acid

n₂M₂ ,V₂ are the n-factor, molarity and volume of base

For a:

Given:

n₁=1

M₁=0.105M

n₂ =1

M₂=0.00950M

V₂= 50.0mL

To find: V₁=?

On substituting the values:

n₁*M₁*V₁= n₂*M₂*V₂

1*0.105*V₁=1*0.00905*50

V₁=4.52mL

Hence, the volume of HCl needed is 4.52 mL

For b:

Given:

n₁=1

M₁=0.105M

n₂ =1

M₂=0.117 M

V₂= 23.0 mL

To find: V₁=?

On substituting the values:

n₁*M₁*V₁= n₂*M₂*V₂

1*0.105*V₁=1*0.117 * 23

V₁=25.63 mL

Hence, the volume of HCl needed is 25.63 mL

For c:

Given:

Mass of NaOH = 1.40 g

Molar mass of NaOH = 40 g/mol

Volume of solution = 1 L

On substituting the values:

Molarity of NaOH = 1.40 /  40

Molarity of NaOH = 0.035M

Given:

n₁=1

M₁=0.105M

n₂ =1

M₂=0.035 M

V₂= 130 mL

To find: V₁=?

On substituting the values:

n₁*M₁*V₁= n₂*M₂*V₂

1*0.105*V₁=1*0.035 * 130

V₁=43.33 mL

Hence, the volume of HCl needed is 43.33 mL.

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