A gas contains 0.1 mol of oxygen and .4 moles of Nitrogen. If the sample is at standard temperature and pressure, what is the partial pressure of nitrogen?

Respuesta :

Answer: The partial pressure of nitrogen is 1.25 atm

Explanation:

From ideal gas equation:

[tex]PV=nRT[/tex]

where,

R = Gas constant = [tex]0.0821\text{ L atm }mol^{-1}K^{-1}[/tex]

T = temperature of the gas = 273K (at STP)

P = pressure of the gas = 1 atm   (at STP)

n = number of moles = 0.1 +0.4 = 0.5

To calculate the partial pressure of the solution, we use the law given by Dalton, which is:

[tex]P_T=\sum_{i=1}^n (p_i\times \chi_i)[/tex]

Or,

[tex]P_T=[(p_{\text{N_2}}\times \chi_{N_2})[/tex]

where,  [tex]\chi_{N_2})[/tex]= mole fraction nitrogen =[tex]\frac{\text {moles of nitrogen}}{\text {total moles}}=\frac{0.4}{0.5}=0.8[/tex]

We are given:

Total pressure = 1 atm

Putting values in above equation, we get:

[tex]1=0.8\times p_{N_2}[/tex]

[tex]p_{N_2}=1.25atm[/tex]

Thus the partial pressure of nitrogen is 1.25 atm