When a specific amount of acetone (C3H6O) is added to 100.0 g of pure water at 65°C, the vapor pressure of water over the solution is lowered by 1.556 kPa. Given the vapor pressure of water at 65°C is 25.022 kPa, what is the mass of acetone added?

Respuesta :

Answer: The mass of acetone that must be added is 4.101 grams

Explanation:

The relative lowering of vapor pressure is directly proportional to the amount of dissolved solute.

The equation used to calculate relative lowering of vapor pressure follows:

[tex]\frac{p^o-p_s}{p^o}=i\times \chi_{solute}[/tex]

where,

[tex]\frac{p^o-p_s}{p^o}[/tex] = relative lowering in vapor pressure  = 1.556 kPa

i = Van't Hoff factor = 1 (for non electrolytes)

[tex]\chi_{solute}[/tex] = mole fraction of solute = ?

[tex]p^o[/tex] = vapor pressure of pure water = 22.022 kPa

Putting values in above equation, we get:

[tex]\frac{1.556}{22.022}=1\times \chi_{acetone}\\\\\chi_{acetone}=0.0707[/tex]

As, the mole fraction of acetone is 0.0707. This means that 0.0707 moles are present in the solution

To calculate the number of moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]

Molar mass of acetone = 58 g/mol

Moles of acetone = 0.0707 moles

Putting values in above equation, we get:

[tex]0.0707mol=\frac{\text{Mass of acetone}}{58g/mol}\\\\\text{Mass of acetone}=(0.0707mol\times 58g/mol)=4.101g[/tex]

Hence, the mass of acetone that must be added is 4.101 grams