An analytical chemist determines that an estuarine water sample contains 1.5 g/liter of sulfate ion (SO4 2). What is the concentration in terms of:(a) g/L of sulfur?(b) Molar concentration of sulfate?(c) Normality?

Respuesta :

Explanation:

It is known that molar mass of [tex]SO^{2-}_{4}[/tex] is as follows.

             Molar mass = [tex]32 + (4 \times 16)[/tex]

                                  = 96 g/mol

It is given that the concentration of [tex]SO^{2-}_{4}[/tex] is 1.5 g/L.

(a) As 96 g of [tex]SO^{2-}_{4}[/tex] contains 32 grams of Sulfur in 1 L. And, 1.5 g of [tex]SO^{2-}_{4}[/tex] contains x grams of sulfur in 1 L.

Therefore, value of x is calculated as follows.

                     x = [tex]\frac{1.5 \times 32}{96}[/tex]

                        = 0.5 g/L

Hence, the concentration of sulfur is 0.5 g/L.

(b)  Now, calculate the molar concentration of sulfur as follows.

             Molarity = [tex]\frac{\text{conc. of sulfate}}{\text{molar mass of SO^{2-}_{4}}}[/tex]

                       = [tex]\frac{1.5 g/L}{96 g/mol}[/tex]

                       = 0.0156 M

Therefore, the molarity of given sample is 0.0156 M.

(c) Calculate the normality as follows.

Equivalent mass of [tex]SO^{2-}_{4}[/tex] = [tex]\frac{96}{2}[/tex]

                                               = 48 g/mol

       Normality = [tex] \frac{conc. of SO^{2-}_{4} in g/L}{equivalent mass of SO^{2-}_{4}}[/tex]

                        = [tex]\frac{1.5 g/L}{48 g/mol}[/tex]

                        = 0.03125 N

Hence, the normality of given sample is 0.03125 N.