Polonium, the largest member of Group 6A, is a rare radioactive metal that is the only element with a crystal structure based on the Simple Cubic unit cell. The density of Polonium is 9.142 g/cm 3 . Calculate an atomic radius for the Polonium atom based on this data.

Respuesta :

Answer:

The atomic radius is:- [tex]1.68\times 10^{-9}\ cm[/tex]

Explanation:

The expression for density is:

[tex]\rho=\frac {Z\times M}{N_a\times {Volume}}[/tex]

[tex]N_a=6.023\times 10^{23}\ {mol}^{-1}[/tex]

M is molar mass of polonium = 209 g/mol

For Simple Cubic unit cell , Z= 1

[tex]\rho[/tex] is the density = 9.142 g/cm³

Thus,  

[tex]Volume=\frac {Z\times M}{N_a\times {\rho}}[/tex]

[tex]Volume=\frac{1\times 209}{6.023\times 10^{23}\times 9.142}\ cm^3[/tex]

[tex]Volume=\frac{209}{10^{23}\times \:55.062266}\ cm^3[/tex]

[tex]Volume=37.95\times 10^{-24}\ cm^3[/tex]

Also, Volume = [tex]{(Edge\ length)}^3[/tex]  

Thus, edge length = [tex]{Volume}^{\frac{1}{3}}[/tex] = [tex]\left(37.95\times \:\:10^{-24}\right)^{\frac{1}{3}}\ cm=3.36\times 10^{-9}\ cm[/tex]

Also, for Simple Cubic unit cell,

[tex]Radius = \frac{Edge\ length}{2}=\frac{3.36\times 10^{-9}}{2}\ cm=1.68\times 10^{-9}\ cm[/tex]

Hence, the atomic radius is:- [tex]1.68\times 10^{-9}\ cm[/tex]