Consider the balanced equation of K I KI reacting with P b ( N O 3 ) 2 Pb(NOX3)X2 to form a precipitate. 2 K I ( a q ) + P b ( N O 3 ) 2 ( a q ) ⟶ P b I 2 ( s ) + 2 K N O 3 ( a q ) 2KI(aq)+Pb(NOX3)X2(aq)⟶PbIX2(s)+2KNOX3(aq) What mass of P b I 2 PbIX2 can be formed by adding 0.528 L of a 0.417 M solution of K I KI to a solution of excess P b ( N O 3 ) 2 Pb(NOX3)X2?

Respuesta :

Answer: 50.7 grams

Explanation:

To calculate the moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text {Molar mass}}[/tex]

a) moles of [tex]KI[/tex]

[tex]\text{Number of moles}=molarity\times {\text {Volume in L]}=0.417M\times 0.528L=0.220moles[/tex]

The balanced chemical equation is:

[tex]2KI(aq)+Pb(NO_3)_2(aq)\rightarrow PbI_2(s)+2KNO_3(aq)[/tex]

[tex]KI[/tex] is the limiting reagent as it limits the formation of product and [tex]Pb(NO_3)_2[/tex] is in excess.

According to stoichiometry :

2 moles of [tex]KI[/tex] give =  1 mole of [tex]PbI_2[/tex]

Thus 0.220 moles of [tex]KI[/tex] give=[tex]\frac{1}{2}\times 0.220=0.110moles[/tex]  of [tex]PbI_2[/tex]

Mass of [tex]PbI_2=moles\times {\text {Molar mass}}=0.110moles\times 461.01g/mol=50.7g[/tex]

Thus 50.7 g of [tex]PbI_2[/tex] will be formed.

50.7 g of precipitate is produced.

The equation of the reaction is; 2KI(aq) + Pb(NO3)2(aq) ⟶ PbI2(s) + 2KNO3 (aq)

We already know from the information in the question that the reactant in excess is Pb(NO3)2.

Number of moles of PbI2= 0.417 M × 0.528 L = 0.22 moles

From the stoichiometry of the reaction;

2 moles of KI yields 1 mole of PbI2

0.22 moles of KI yields  0.22 moles × 1 mole/2 moles

= 0.11 moles of PbI2

Mass of PbI2produced = number of moles of PbI2×  molar mass of PbI2

Molar mass of PbI2= 461 g/mol

Mass of PbI2produced = 0.11 moles of PbI2× 461 g/mol = 50.7 g of PbI2

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