Benzoic acid is a weak acid that has antimicrobial properties. Its sodium salt, sodium benzoate, is a preservative found in foods, medications, and personal hygiene products. Benzoic acid ionizes in water:
C6H5COOH⇌C6H5COO−+H+ The pKa of this reaction is 4.2. In a 0.57 M solution of benzoic acid,
A. what percentage of the molecules are ionized?
B. Express your answer to two significant figures and include the appropriate units.

Respuesta :

Answer:

The percentage of molecules that are ionized is 1,1%

Explanation:

For the reaction:

C₆H₅COOH ⇌ C₆H₅COO⁻ + H⁺. The ka, 10^(-4,2), is defined as:

[tex]10^{-4,2} =\frac{ [C_6H_5COO^-][H^+]}{[C_6H_5COOH]}[/tex]

The molar concentrations in equilibrium are:

[C₆H₅COOH] = 0,57-x

[C₆H₅COO⁻] = x

[H⁺] = x

Replacing:

[tex]10^{-4,2} =\frac{ [x][x]}{[0,57-x]}[/tex]

3,6x10⁻⁵-6,3x10⁻⁵x = x²

0 = x² + 6,3x10⁻⁵x - 3,6x10⁻⁵

Resolving for x:

x = -0.006 Wrong answer, there are not negative concentrations

x = 0,006 Real answer

That means that:

[C₆H₅COOH] = 0,57-0,006 = 0,564M

[C₆H₅COO⁻] = 0,006M

The percentage of molecules ionized is [C₆H₅COO⁻]/initial[C₆H₅COOH], thus:

0,006M/0,57M×100 = 1,1%

I hope it helps