A reaction between substances Y and Z is
representedstochiometrically by
Y2 + Z2 ---> 2YZ


The rate constant obeys the Arrhenius equation. At 435.
K
the rate constant is k = 2.95 e-03 L/mol-s and A = 3.00 e+10
L/mol-s
What is the activation energy (KJ/mol) for
thisreaction?

Respuesta :

Answer : The value of activation energy for this reaction is 108.318 kJ/mol

Explanation :

The Arrhenius equation is written as:

[tex]K=A\times e^{\frac{-Ea}{RT}}[/tex]

Taking logarithm on both the sides, we get:

[tex]\ln k=-\frac{Ea}{RT}+\ln A[/tex]             ............(1)

where,

k = rate constant  = [tex]2.95\times 10^{-3}L/mol.s[/tex]

Ea = activation energy  = ?

T = temperature = 435 K

R = gas constant  = 8.314 J/K.mole

A = pre-exponential factor  = [tex]3.00\times 10^{+10}L/mol.s[/tex]

Now we have to calculate the value of rate constant by putting the given values in equation 1, we get:

[tex]\ln (2.95\times 10^{-3}L/mol.s)=-\frac{Ea}{8.314J/K.mol\times 435K}+\ln (3.00\times 10^{10}L/mol.s)[/tex]

[tex]Ea=108318.365J/mol=108.318kJ/mol[/tex]

Therefore, the value of activation energy for this reaction is 108.318 kJ/mol