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Electron density on Cl atom depends on electronegativity difference between Cl and other bonded atom. If the electrnegativity difference is more then Cl has greater electron density, that menas if the bonded atom has less electronegativity then bonded electrons are more attracted by Cl and it has greater electron density.
Among the five atoms which are bonded to Cl atom H has low electronegativity. So in H-Cl two bonded electrons are closer to Cl atom as it has greater electronegativity than H. This results more electron density on Cl atom.
Hence in H-Cl bond Cl atom have the highest electron density
Hope this helps!
The bond in which the chlorine atom has the highest electron density is H − C l.
The polarity of a bond depends on the magnitude of electronegativity difference between the atoms in the bond. The greater the electronegativity difference between the atoms in a bond the more the polarity of the bond.
The magnitude of electron density on each atom in a bond depends on its electronegativity. The more electronegative an atom is, the more it is able to accommodate larger electron density. Looking at the options, hydrogen is far less electronegative than chlorine so a large magnitude of electron density resides on the chlorine atom in HCl.
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