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At a certain temperature the rate of this reaction is first order in HI with a rate constant of :0.0632s

2HIg=H2g+I2g Suppose a vessel contains HI at a concentration of 1.28M . Calculate how long it takes for the concentration of HI to decrease to 17.0% of its initial value. You may assume no other reaction is important. Round your answer to 2 significant digits.

Respuesta :

Answer : The time taken for the reaction is, 28 s.

Explanation :

Expression for rate law for first order kinetics is given by :

[tex]k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}[/tex]

where,

k = rate constant  = 0.0632

t = time taken for the process  = ?

[tex][A_o][/tex] = initial amount or concentration of the reactant  = 1.28 M

[tex][A][/tex] = amount or concentration left time 't' = [tex]1.28\times \frac{17}{100}=0.2176M[/tex]

Now put all the given values in above equation, we get:

[tex]0.0632=\frac{2.303}{t}\log\frac{1.28}{0.2176}[/tex]

[tex]t=28s[/tex]

Therefore, the time taken for the reaction is, 28 s.