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The rate constant of a reaction is 5.8 × 10−3 s−1 at 25°c, and the activation energy is 33.6 kj/mol. what is k at 75°c? enter your answer in scientific notation.

Respuesta :

Answer:

k₂ = 4.06 x 10⁻² s⁻¹.

Explanation:

  • From Arrhenius law: K = Ae(-Ea/RT)

where, K is the rate constant of the reaction.

A is the Arrhenius factor.

Ea is the activation energy.

R is the general gas constant.

T is the temperature.

  • At different temperatures:

ln(k₂/k₁) = Ea/R [(T₂-T₁)/(T₁T₂)]

k₁ = 5.8 × 10⁻³ s⁻¹, k₂ = ??? , Ea = 33600 J/mol, R = 8.314 J/mol.K, T₁ = 298.0 K, T₂ = 348.0 K.

  • ln(k₂/5.8 × 10⁻³ s⁻¹) = (33600 J/mol / 8.314 J/mol.K) [(348.0 K - 298.0 K) / (298.0 K x 348.0 K)] = (4041.37) (4.82 x 10⁻⁴) = 1.9479.
  • Taking exponential of both sides:

(k₂/5.8 × 10⁻³ s⁻¹) = 7.014.

∴ k₂ = 4.06 x 10⁻² s⁻¹.

The study of chemicals and bonds is called chemistry. There are different types of elements and are metals and nonmetals,

The correct answer to the question is k₂ = 4.06 x 10⁻² s⁻¹.

What is Arrhenius law?

  • The Arrhenius equation is a formula for the temperature dependence of reaction rates

From Arrhenius law:

[tex]K = Ae(\frac{-Ea}{RT})[/tex] where,

  • K is the rate constant of the reaction.
  • A is the Arrhenius factor.
  • Ea is the activation energy.
  • R is the general gas constant.
  • T is the temperature.

At different temperatures:

[tex]ln\frac{k_2}{k_1} = \frac{Ea}{R}\frac[{(T_2-T_1)}{(T_1T_)}[/tex]

All the data is given as follows:-

  • k₁ = 5.8 × 10⁻³ s⁻¹,
  • Ea = 33600 J/mol,
  • R = 8.314 J/mol.K,
  • T₁ = 298.0 K
  • T₂ = 348.0 K.

[tex]ln(\frac{k_2}{5.8 * 10^{-3}}) = \frac{33600}{8.314} *\frac{(348.0 K - 298.0 K)}{(298.0 K* 348.0 K)} \\\\= (4041.37) (4.82 x 10^{-4}) = 1.9479.[/tex]

Taking exponential of both sides:

[tex]\frac{k_2}{5.8* 10^{-3}}\\ \\= 7.014.[/tex]

Hence, the correct answer is k₂ = 4.06 x 10⁻² s⁻¹.

For more information about the rate constant, refer to the link:-

https://brainly.in/question/9531558