An electrochemical cell has the following standard cell notation.

Mg(s) | Mg^2+ (aq) || Aq^+(aq) | Aq(s)

What is the standard potential for the cell?

Is this a spontaneous or non spontaneous reaction? Explain your answer.

Is this a galvanic cell or an electrolytic cell? Explain your answer.

Respuesta :

Explanation:

The given following standard cell notation.  

Mg(s) | Mg^2+ (aq) || Aq^+(aq) | Aq(s)

Oxidation: In this chemical process the electrons are lost by the element to form cation

[tex]Mg(s)\rightarrow Mg^{2+}+2e^-[/tex]....(1)

Reduction: In this chemical process the electrons are gained by the element to form anion.

[tex]Ag^+(aq)+1e^-\rightarrow Ag(s)[/tex]...(2)

Overall redox reaction: (1)+2 × (2)

[tex]Mg(s)+2Ag^+(aq)\rightarrow Mg^{2+}+2Ag(s)[/tex]

Answer:

The standard potential for the cell is: 3.17 V

The reaction is spontaneous

It is a galvanic cell

Explanation:

The half-reactions for each process are:

Oxidation: Mg(s) -> Mg^2+ (aq) + 2e^-   E^0 = 2.37

Reduction: Ag^+ (aq) + 1e^-  -> Ag(s)      E^0 = 0.8

The standard potential for the cell is:

E^0 cell = E^0 reduction + E^0 oxidation = 2.37 + 0.8 =  3.17 V

The reaction is spontaneous because the standard potential for the cell is positive.

It is a galvanic cell. In a galvanic cell, spontaneous redox processes occur allowing the continuous flow of electrons through the conductor, whereas, in an electrolytic cell, the non-spontaneous redox reactions are promoted by an external source of current.