Here we have to choose the statement which correctly describe the reaction NH₄ClO₄ (s) + Al (s) → Al₂O₃ (g) + HCl (g) + N₂ (g) + H₂O (g).
The correct statement for the reaction:
NH₄ClO₄ (s) + Al (s) → Al₂O₃ (g) + HCl (g) + N₂ (g) + H₂O (g) is 4. aluminum is reducing agent.
The reaction between ammonium perchlorate and aluminium metal as given:
NH₄ClO₄ (s) + Al (s) → Al₂O₃ (g) + HCl (g) + N₂ (g) + H₂O (g)
In this reaction the change of oxidation state of each element is:
a) nitrogen (N) from -3 to 0 thus oxidation. Thus nitrogen is oxidized in this reaction.
b) chlorine (Cl) from +7 to -1 thus reduction. Thus chlorine is reduced in this reaction.
c) Aluminum (Al) from 0 to +3 state thus oxidation. Al is loosing electrons; Thus aluminum is being oxidized.
We know the gaining of electron is a reducing process and the compound itself is an oxidizing agent, whereas the loosing of electrons is a oxidation process and the compound itself is an reducing agent.
Thus aluminum is a reducing agent in this reaction.